III. The vertical pressure structure of the atmosphere A. Although we're not constantly aware of it, air is a tangible, material substance, and, therefore, it has mass. Anything with mass is subject to gravity. So, air, responding to gravity, exerts pressure on any surface exposed to it. B. The reason we're not conscious of it is that our bodies exert as much pressure outward as the air exerts down and in on us: The two pressures balance each other out. C. At sea level, this pressure amounts to about 1 kg/cm2 and it declines quite rapidly the higher we go (that would be a tad under 15 lb./sq. in.) 1. If we were to examine any given square centimeter at sea level and imagine all the air lying above it in an imaginary cylinder clear out to the edge of the atmosphere, 10,000 km up, that column of air would weigh 1 kg. Picture this column 10,000 km tall, with a square cross-section 1 cm on a side at sea level and tapering out to about 2.5 cm at the other end. 2. The higher you go in that column, the less air is sitting on top of you, so it weighs less and less. a. Air is very compressible, unlike liquids and solids. b. So, air is densest toward the bottom of our imaginary column of air, because more of it is compressed down there by the weight of all the air molecules above it. c. Compression, then, falls off with elevation in that column. There is, then, an inverse relationship between air pressure and altitude above ground. The higher you go, the less air is pressing down on you, so density and weight dwindle. 3. The rate of this fall off in air pressure is about 1/30th of itself for every 275 m gain in altitude (~900 ft.). That is, if air pressure were 1 kg/cm2 at sea level, it would be 0.97 at 275 m, 0.93 at 550 m, 0.90 at 825 m, and so on. a. Actually, it's a little more complicated than that, because air pressure is a function not just of altitude, but also of temperature and proportion of water vapor in it. b. All things being equal (which, of course, they rarely are), the greater the temperature, the greater the pressure (Gay-Lussac Law): Hotter air means more energetically moving air molecules, which means more pressure from all those higher-speed collisions. c. Humid air is less dense than dry air (water molecules with a molecular weight of 18 displace nitrogen and oxygen molecules with molecular weights of 30 and 32, respectively) and, so, exerts less pressure. d. All these caveats out of the way, the exponential rate of falloff in air pressure with increasing altitude can be graphed: 4. A cool experiment established that air is a material substance with mass that exerts pressure on anything exposed to it: It was devised by Evangelista Torricelli (one of Galileo's students) back in 1643!!! a. He closed off one end of a glass tube about 1.2 m long (~4 ft.) and then filled it with mercury, a liquid metal (and a very toxic one at that), and flipped it over into a dish. A bunch of the "quicksilver" ran out of the tube and into the dish but not all of it (and a good thing, too, or Torricelli would have had himself an early toxic waste spill in his lab!). Only about 45 cm or so ran down and out of the tube, leaving a column about 76 cm tall (760 mm or 29.92 in.). And a clean lab table. b. He reasoned that something was pressing down on the open surface of mercury in the dish, enough to support the weight of a column of mercury in the tube about 760 mm tall. That something, he figured, was air pressure. c. He used mercury because, if he used water, the water, being lighter than mercury, would need a tube a lot longer. When he was looking around for a suitable liquid for his famous experiment, Galileo suggested mercury to him. d. Torricelli correctly deduced that mercury, rising only about 1/14 as high as water, must be about 14 times denser than water. e. He also figured out that there must be a vacuum between the top of the column of mercury and the end of the glass tube. f. This must have annoyed him: The level of the mercury column varied somewhat from one day to another. He commented on it and deduced that air pressure itself must vary to produce this change. g. This experiment, which rocked the science of the 17th century, became the parent of the mercury barometer, which is still used today as one way of measuring ("-meter") barometric pressure ("baro-"). h. This gizmo is what the TV weather reporters are referring to when they talk about air pressure being "28.3 inches and rising" or when weathercasters elsewhere talk about "785 mm and falling." 5. The importance of air pressure (getting personal). a. Our lungs can extract oxygen from the air at the air pressures (and, implicitly, the molecular densities) that our species has normally encountered. i. This mechanism breaks down on us if we wander off into elevations our ancestors did not hang out in and survive to leave us their genes. This is mountain sickness. Your body is pressing out harder than the atmosphere is pressing in, so bits of you start leaking out (nosebleeds) and your blood vessels expand (giving you headaches), and you get weak because your red blood cells aren't carrying the load of oxygen to which they're accustomed. Within limit, we can adapt a bit: If you go camping at high elevations, say above 3,000 meters, you'll be pretty wretched for a day or two and then your body adapts. Go much higher and you begin to get out of the range of our genetic adaptability, and you can die. ii. This is why jets are pressurized when they fly at their favored 10,000-15,000 meters and why, when a plane's external structure is seriously ruptured, there is an explosive outrush of its contents near the rupture (remember those nine people that got sucked out the back of their 747 when a 40 foot hole blew open in its fuselage over the Pacific just south of Hawai'i back in 1989 and the guy in Brazil who got pulled out of a plane in 1997?). Even if the plane doesn't explosively discharge its contents, sudden depressurization causes people to lose consciousness almost instantly and die a few minutes later -- remember Payne Stewart, and his companions in 1999? b. Another homely example is cooking (not that I know anything about it!<G>) i. Water boils at 100° C at sea level (that would be 212° F). The boiling point drops about 1° C for every 165 meters of elevation (1° F for every 889 feet). ii. This means that the higher you are, the cooler the water is when it boils, so that is why you have to take longer to cook food at higher elevations (and a pressure cooker helps you cook faster). iii. I have a terrible anecdote about the ramifications of forgetting this important bit of geographical information! A friend of mine at Jet Propulsion Lab told me about a group of guys there that like to go off camping now and again. One of the guys fancies himself a gourmet cook. On one of their trips, they went into the High Sierra, and Mr. Gourmet had brought ... lentils to make a custom stew. They set up camp and le gourmet put the lentils on to boil mid-day. They boiled. And boiled. And boiled. And were not getting cooked, remaining adamantly chewy despite hours of boiling. Pretty soon, it was starting to get dark, and everyone else was getting hungry. An executive decision was made to just put in the other ingredients and finish making the stew. As darkness descended, they supped on the still very chewy lentil stew, which was hideous. Then, they all turned in for the night. And faced the consequences of forgetting about Boyle's Gas Law. a. Time out for an important announcement about Boyle's Law, named after Robert Boyle who figured it out in the 18th century. b. Boyle figured out that there is a relationship between gas pressure and the volume gas occupies. Reduce the volume into which you cram X molecules of gas, and you thereby raise the gas pressure. If you reduce the gas pressure, the gas will expand into a larger volume. c. Back to our regularly scheduled anecdote... iv. Being at high elevation, the JPL rocket scientists were in an area of significantly reduced air pressure. Lentils are, er, how to put this delicately? gas-producing, particularly when they haven't been cooked enough. Which these hadn't, because of the unanticipated drop in the boiling point of water with elevation. In the middle of the night, Boyle's Law hit them, first in the stomach and then in the intestines, as the gas expanded in the reduced pressure of the Sierra, producing extreme human wretchedness, both of the stomach-cramping and bloating variety and of the aromatic variety. None of them got much sleep. Which meant they were murderously disposed toward the author of their discomfort and embarrassment and, I understand, the man is under vigilante sentence of death if he ever even fantasizes about gourmet lentils in the piney woods again! v. I had my rocket scientist pal check out this anecdote. He affirmed it was accurate as to the facts, but he thought that the Boyle's Law dimension would not apply unless the lentils were eaten at lower elevation and then they climbed to higher elevation. I didn't buy that, because, no matter where you ate them, they might be expected to generate a certain number of CH4 gas molecules in digestion, which should be invariant whether you were at low or high elevations. With the same number of gas molecules and the lower air pressure at high elevation, I should think you'd be in for an unusually bad bout of bloat. The rocket scientist has come to endorse this conclusion! ;-) Come away from this lecture knowing that pressure is inversely related to altitude, that Torricelli's experiment is the basis of the modern barometer, and the core idea of Boyle's Law (given the same number of gas molecules, pressure is inversely related to volume) and Gay-Lussac's Law (temperature and pressure are directly related to one another, if all else is equal). In the next lecture, I'll discuss the vertical thermal structure.
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Rodrigue
First placed on web: 10/08/00
Last revised: 02/17/01