Geography 140
Introduction to Physical Geography

Lecture: Vertical Pressure Structure of the Atmosphere

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III. The vertical pressure structure of the atmosphere 
     A. Although we're not constantly aware of it, air is a tangible, material 
        substance, and, therefore, it has mass.  Anything with mass is subject 
        to gravity.  So, air, responding to gravity, exerts pressure on any 
        surface exposed to it.
     B. The reason we're not conscious of it is that our bodies exert as much 
        pressure outward as the air exerts down and in on us:  The two 
        pressures balance each other out.
     C. At sea level, this pressure amounts to about 1 kg/cm2 and 
        it declines quite rapidly the higher we go (that would be a tad under 
        15 lb./sq. in.)
        1. If we were to examine any given square centimeter at sea level and 
           imagine all the air lying above it in an imaginary cylinder clear 
           out to the edge of the atmosphere, 10,000 km up, that column of air 
           would weigh 1 kg.  Picture this column 10,000 km tall, with a 
           square cross-section 1 cm on a side at sea level and tapering out 
           to about 2.5 cm at the other end.  
        2. The higher you go in that column, the less air is sitting on top of 
           you, so it weighs less and less.
           a. Air is very compressible, unlike liquids and solids.
           b. So, air is densest toward the bottom of our imaginary column of 
              air, because more of it is compressed down there by the weight 
              of all the air molecules above it.
           c. Compression, then, falls off with elevation in that column.  
              There is, then, an inverse relationship between air pressure and 
              altitude above ground.  The higher you go, the less air is 
              pressing down on you, so density and weight dwindle.
        3. The rate of this fall off in air pressure is about 1/30th of itself 
           for every 275 m gain in altitude (~900 ft.).  That is, if air 
           pressure were 1 kg/cm2 at sea level, it would be 0.97 at 
           275 m, 0.93 at 550 m, 0.90 at 825 m, and so on.  
           a. Actually, it's a little more complicated than that, because air 
              pressure is a function not just of altitude, but also of 
              temperature and proportion of water vapor in it.
           b. All things being equal (which, of course, they rarely are), the 
              greater the temperature, the greater the pressure (Gay-Lussac 
              Law):  Hotter air means more energetically moving air molecules, 
              which means more pressure from all those higher-speed 
              collisions.
           c. Humid air is less dense than dry air (water molecules with a 
              molecular weight of 18 displace nitrogen and oxygen molecules 
              with molecular weights of 30 and 32, respectively) and, so, 
              exerts less pressure.
           d. All these caveats out of the way, the exponential rate of 
              falloff in air pressure with increasing altitude can be graphed:

              [ graph of air pressure with altitude ]

        4. A cool experiment established that air is a material substance with 
           mass that exerts pressure on anything exposed to it:  It was 
           devised by Evangelista Torricelli (one of Galileo's students) back 
           in 1643!!!
           a. He closed off one end of a glass tube about 1.2 m long (~4 ft.) 
              and then filled it with mercury, a liquid metal (and a very 
              toxic one at that), and flipped it over into a dish.  A bunch of 
              the "quicksilver" ran out of the tube and into the dish but not 
              all of it (and a good thing, too, or Torricelli would have had 
              himself an early toxic waste spill in his lab!).  Only about 45 
              cm or so ran down and out of the tube, leaving a column about 76 
              cm tall (760 mm or 29.92 in.). And a clean lab table.
           b. He reasoned that something was pressing down on the open surface 
              of mercury in the dish, enough to support the weight of a column 
              of mercury in the tube about 760 mm tall.  That something, he 
              figured, was air pressure.
           c. He used mercury because, if he used water, the water, being 
              lighter than mercury, would need a tube a lot longer.  When he 
              was looking around for a suitable liquid for his famous 
              experiment, Galileo suggested mercury to him.
           d. Torricelli correctly deduced that mercury, rising only about 
              1/14 as high as water, must be about 14 times denser than water.
           e. He also figured out that there must be a vacuum between the top 
              of the column of mercury and the end of the glass tube. 
           f. This must have annoyed him:  The level of the mercury column 
              varied somewhat from one day to another.  He commented on it and 
              deduced that air pressure itself must vary to produce this 
              change. 
           g. This experiment, which rocked the science of the 17th century, 
              became the parent of the mercury barometer, which is still used 
              today as one way of measuring ("-meter") barometric pressure 
              ("baro-").
           h. This gizmo is what the TV weather reporters are referring to 
              when they talk about air pressure being "28.3 inches and rising" 
              or when weathercasters elsewhere talk about "785 mm and 
              falling."
        5. The importance of air pressure (getting personal).
           a. Our lungs can extract oxygen from the air at the air pressures 
              (and, implicitly, the molecular densities) that our species has 
              normally encountered. 
                i. This mechanism breaks down on us if we wander off into 
                   elevations our ancestors did not hang out in and survive to 
                   leave us their genes.  This is mountain sickness.  Your 
                   body is pressing out harder than the atmosphere is pressing 
                   in, so bits of you start leaking out (nosebleeds) and your 
                   blood vessels expand (giving you headaches), and you get 
                   weak because your red blood cells aren't carrying the load 
                   of oxygen to which they're accustomed.  Within limit, we 
                   can adapt a bit:  If you go camping at high elevations, say 
                   above 3,000 meters, you'll be pretty wretched for a day or 
                   two and then your body adapts.  Go much higher and you 
                   begin to get out of the range of our genetic adaptability, 
                   and you can die.
               ii. This is why jets are pressurized when they fly at their 
                   favored 10,000-15,000 meters and why, when a plane's 
                   external structure is seriously ruptured, there is an 
                   explosive outrush of its contents near the rupture 
                   (remember those nine people that got sucked out the back of 
                   their 747 when a 40 foot hole blew open in its fuselage 
                   over the Pacific just south of Hawai'i back in 1989 and the 
                   guy in Brazil who got pulled out of a plane in 1997?).  
                   Even if the plane doesn't explosively discharge its 
                   contents, sudden depressurization causes people to lose 
                   consciousness almost instantly and die a few minutes later 
                   -- remember Payne Stewart, and his 
                   companions in 1999?
           b. Another homely example is cooking (not that I know anything 
              about it!<G>)  
                i. Water boils at 100° C at sea level (that would be 
                   212° F).  The boiling point drops about 1° C for 
                   every 165 meters of elevation (1° F for every 889 
                   feet).
               ii. This means that the higher you are, the cooler the water is 
                   when it boils, so that is why you have to take longer to 
                   cook food at higher elevations (and a pressure cooker helps 
                   you cook faster).
              iii. I have a terrible anecdote about the ramifications of 
                   forgetting this important bit of geographical information!  
                   A friend of mine at Jet Propulsion Lab told me about a 
                   group of guys there that like to go off camping now and 
                   again.  One of the guys fancies himself a gourmet cook.  On 
                   one of their trips, they went into the High Sierra, and Mr. 
                   Gourmet had brought ... lentils to make a custom stew.  
                   They set up camp and le gourmet put the lentils on 
                   to boil mid-day.  They boiled.  And boiled. And boiled.  
                   And were not getting cooked, remaining adamantly chewy 
                   despite hours of boiling.  Pretty soon, it was starting to 
                   get dark, and everyone else was getting hungry.  An 
                   executive decision was made to just put in the other 
                   ingredients and finish making the stew.  As darkness 
                   descended, they supped on the still very chewy lentil stew, 
                   which was hideous.  Then, they all turned in for the night.  
                   And faced the consequences of forgetting about Boyle's Gas 
                   Law.  
                   a. Time out for an important announcement about Boyle's 
                      Law, named after Robert Boyle who figured it out in the 
                      18th century.
                   b. Boyle figured out that there is a relationship between 
                      gas pressure and the volume gas occupies.  Reduce the 
                      volume into which you cram X molecules of gas, and you 
                      thereby raise the gas pressure.  If you reduce the gas 
                      pressure, the gas will expand into a larger volume.  
                   c. Back to our regularly scheduled anecdote...
               iv. Being at high elevation, the JPL rocket scientists were in 
                   an area of significantly reduced air pressure.  Lentils 
                   are, er, how to put this delicately? gas-producing, 
                   particularly when they haven't been cooked enough.  Which 
                   these hadn't, because of the unanticipated drop in the 
                   boiling point of water with elevation.  In the middle of 
                   the night, Boyle's Law hit them, first in the stomach and 
                   then in the intestines, as the gas expanded in the reduced 
                   pressure of the Sierra, producing extreme human 
                   wretchedness, both of the stomach-cramping and bloating 
                   variety and of the aromatic variety.  None of them got much 
                   sleep.  Which meant they were murderously disposed toward 
                   the author of their discomfort and embarrassment and, I 
                   understand, the man is under vigilante sentence of death if 
                   he ever even fantasizes about gourmet lentils in the piney 
                   woods again! 

                v. I had my rocket scientist pal check out this anecdote. He 
                   affirmed it was accurate as to the facts, but he thought 
                   that the Boyle's Law dimension would not apply unless the 
                   lentils were eaten at lower elevation and then they climbed 
                   to higher elevation.  I didn't buy that, because, no matter 
                   where you ate them, they might be expected to generate a 
                   certain number of CH4 gas molecules in digestion, which 
                   should be invariant whether you were at low or high 
                   elevations.  With the same number of gas molecules and the 
                   lower air pressure at high elevation, I should think you'd 
                   be in for an unusually bad bout of bloat.  The rocket 
                   scientist has come to endorse this conclusion!  ;-)


Come away from this lecture knowing that pressure is inversely related to 
altitude, that Torricelli's experiment is the basis of the modern barometer, 
and the core idea of Boyle's Law (given the same number of gas molecules, 
pressure is inversely related to volume) and Gay-Lussac's Law (temperature and 
pressure are directly related to one another, if all else is equal).

In the next lecture, I'll discuss the vertical thermal structure.

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Document and © maintained by Dr. Rodrigue
First placed on web: 10/08/00
Last revised: 02/17/01

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